Kamil Klier

University Distinguished Professor Emeritus
Seeley G. Mudd, Room 595
Research Interests: 
relations between the structure and physical properties of solids
surface properties
Teaching Interests: 
Introductory Chemistry
Solid State Chemistry
Physical Inorganic Chemistry
Quantum Mechanics
Surface Spectroscopy

Research into the relations between the structure and physical properties of solids, their surface properties, and their ability to guide chemical reactions along specific pathways. Solid state chemistry and catalysis phenomena are investigated by modern means of electron and optical spectroscopies and electron microscopy involving microdiffraction and X-ray microanalysis. OLEDs and PLEDs.

Surface science of atomic and molecular overlayers is being pursued using high energy and angle resolution X-ray and UV photoelectron spectroscopy (HR X(U)PS), electron energy loss spectroscopy (HR EELS), low energy electron diffraction (LEED), temperature programmed desorption (TPD), and isotope methods.

Quantum chemical state-of-the-art studies are carried out of the reaction pathways and the structure of surface complexes using all-electron methods, including calculations of core-level chemical shifts for HR X(U)PS.

Established an NSF-sponsored program in "Chemistry of Materials Synthesis and Processing", a 5-year B.S./M.S. program which bridges undergraduate and graduate education. Directed the Hewlett Grant Program for Freshmen and Sophomores in Chemistry, Materials, Physics, Chemical Engineering, and Biosciences.

Chemical demonstrations in introductory courses are designed, assembled, and published, e.g. "Diffraction of a Laser Light by a Memory Chip," K. Klier and J.A. Taylor, J. Chem. Ed. 68 , (1991) 155.

Selected Publications:

"Spectroscopic Studies of Zeolites and Mesoporous Materials," K. Klier, in Studies in Surface Science and Catalysis 157 (2005) 205-224.

"Ion Exchange, Core-Level Shifts, and Bond Strengths in Mesoporous Solid Acid SBA-15," J.L. Smith**, R.G. Herman, and K Klier*, in "Molecular Sieves: From Basic Research in Industrial Applications" Studies in Surface Science and Catalysis 158A (2005) 797-804.

"SBA-Catalyzed Synthesis of Ethers from Alcohols," S.S. Hasan**, R.G. Herman, and K. Klier*, in "Molecular Sieves: From Basic Research to Industrial Applications" Studies in Surface Science and Catalysis 158B (2005) 1343-1350.

"A Critical Assessment of Two Predictive Models of Binary Vapor-Liquid Equilibrium", M.L. Neiman*, H. Cheng*, V. Parekh, B. Peterson and K. Klier, Phys. Chem Chem. Phys. 6 (2004) 3474-3483.

"Electronic Structure and Reactivity of Defect MoS2 II. Bonding and Activation of Hydrogen on Surface Defect Sites and Clusters", J.A. Spirko, M.L. Neiman, A.M. Oelker and K. Klier*, Surface Science 572 (2004) 191-205.

"Dehydrocondensation of Alcohols to Form Ethers Over Mesoporous SBA-15 Catalyst", R.G. Herman, F.H. Khouri, K Klier*, J.B. Higgins, M.R. Galler and C.T. Terenna, Journal of Catalysis 228 (2004) 347-36.

"Sorption of Nitrogen Bases and XPS Study of Mesoporous Solid Acid SBA-15", J.L. Smith, R.G. Herman, C.R. Terenna, M.R. Galler and K. Klier*, Journal of Physical Chemistry A 108 (2004) 39-46.

J.A. Spirko, M.L. Neiman, A.M. Oelker and K. Klier* "Electronic Structure and Reactivity of Defect MoS2 I. Relative Stabilities of Clusters and Edges, and Electronic Surface States", Surface Science 542 (2003) 192-204.

K.T. Park, A.C. Miller, K. Klier, R.L. Opila, J.E. Rowe, "Heteroepitaxial Copper Phthalocyanine on Au(001) Studied by High-Resolution X-Ray Photoelectron Spectroscopy", Surface Science Letters 529 (2003) L285-L292.